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Информация
Eng»Ukraine»Waterproofing, protection and repair of buildings, restoration of structures»Bitumens for construction, roofing, brittle, insulating, road, special, liquefied»Roofing bitumen impregnating BNK Ecobit GOST 9548-74 (DSTU 4818:2007)

BNK 45/190 Ecobit DSTU 4818:2007 roofing bitumen

1. BRANDS

1.1. Depending on the application, roofing bitumens are produced in the following brands:

BNK-40/180 Ecobit - bitumen for impregnation;

BNK-45/190 Ecobit - bitumen for impregnation and obtaining a covering bitumen;

BNK-90/30 Ecobit - bitumen for the covering layer.

1.2. Roofing bitumen grades are obtained:

BNK-40/180 Ecobit - by oxidation of residues from atmospheric-vacuum distillation of oils;

BNK-45/190 Ecobit - by oxidation of raw materials for the production of roofing bitumen according to regulatory and technical documentation;

BNK-90/30 Ecobit - oxidation of bitumen grade BNK 45/190 Ecobit or raw materials for the production of roofing bitumen according to regulatory and technical documentation.

 

2. ACCEPTANCE RULES

2.1. Roofing petroleum bitumens are accepted in batches. A batch is any amount of bitumen that is uniform in quality indicators and accompanied by one quality document. 

2.2. Sample size - according to GOST 2517. 

2.3. The manufacturer determines the mass fraction of water periodically at least once every 6 months.

Solubility in toluene or chloroform and the mass fraction of paraffin are determined periodically at least once every 3 months..

If unsatisfactory results are obtained from periodic tests, the manufacturer transfers the tests for this indicator to acceptance tests until positive results are obtained for at least three consecutive batches.

(Amended version, Amendment No. 4).

2.4. If unsatisfactory test results are obtained for at least one indicator, repeat tests are carried out on a newly selected sample from a doubled selection. The results of the repeat tests apply to the entire batch.

 

3. TEST METHODS

3.1. Samples of roofing petroleum bitumen are taken in accordance with GOST 2517. The mass of the combined sample of bitumen of each grade is 0.5 kg.

(Amended version, Amendment No. 3).

 

4. PACKAGING, MARKING, TRANSPORTATION AND STORAGE

4.1. Packaging, marking, transportation and storage of roofing bitumens according to GOST 1510. Transportation of roofing bitumens in tank trucks and bunker gondola cars is permitted. 

4.2. Petroleum roofing bitumens belong to the 9th class of transport hazard according to GOST 19433 (subclass 9.2, category 9.21, classification code 921).

(Additionally introduced, Amendment No. 5).

 

5. MANUFACTURER\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\'S WARRANTY

5.1. The manufacturer guarantees that roofing petroleum bitumens comply with the requirements of this standard. 

5.2. The guaranteed shelf life of roofing petroleum bitumens is one year from the date of manufacture.

5.1, 5.2. (Amended version. Amendment No. 3). 

 

6. SAFETY REQUIREMENTS

6.1. Petroleum roofing bitumens are flammable substances with a flash point of at least 240 °C. The minimum autoignition temperature is 300 °C according to GOST 12.1.044. 

6.2. Petroleum bitumens are low-hazard substances and, in terms of their impact on the human body, belong to hazard class 4 according to GOST 12.1.007. Fumes of molten bitumen have a moderate irritating effect on the skin and mucous membranes of the eyes and upper respiratory tract. The cumulative effect is not pronounced. 

6.3. The maximum permissible concentration of petroleum bitumen vapors is adopted for aliphatic hydrocarbons C1 - C10 (in terms of C) and is 300 mg/m3 in the air of the working zone according to GOST 12.1.005. The content of hydrocarbon vapors in the air is determined by the chromatographic method.

6.4. Petroleum bitumens do not form toxic compounds in the air and waste water in the presence of other substances or factors.

6.5. Those working with petroleum bitumen must be provided with personal protective equipment in accordance with standard industry standards for the issuance of special clothing, special footwear and other personal protective equipment: filter gas masks according to GOST 12.4.034*, suits according to GOST 12.4.111 and GOST 12.4.112, footwear according to GOST 12.4.032, gloves according to GOST 12.4.010 and protective glasses according to GOST 12.4.013**. There are no special requirements for personal hygiene.

6.6. If heated petroleum bitumen gets on exposed areas of skin, it must be cooled under running water, the bitumen must be removed with petroleum jelly, and the victim must be given assistance as for thermal burns.

6.7. The room in which work with bitumen is carried out must be equipped with supply and exhaust ventilation.

6.8. If small quantities of bitumen catch fire, extinguish with sand, felt or a foam fire extinguisher. Extinguish developed fires with a foam jet.

6.9. Bitumen production waste - oxidation gases - are rendered harmless by burning in an afterburner.

 

Item No.

Name of indicators

БNK-40/180 Ecobit 

БNK-45/190 Ecobit 

БNK-90/30 Ecobit 

Test method

1

Needle penetration depth at 25°C, 0.1 mm

160-210

160-220

25-35

According to GOST 11501

2

Ring and ball softening temperature, °C

37-44

40-50

80-95

According to GOST 11506

3

Brittleness temperature, °C, not higher

-

-

-10

According to GOST 11505

4

Solubility in toluene or chloroform, %, not less than

99,50

99,50

99,50

According to GOST 20739

5

Change in mass after heating, %, no more than

0,80

0,80

0,50

According to GOST 18180

6

Flash point °C, not lower

230

240

240

According to GOST 4333

7

Mass fraction of water

Traces

Traces

Traces

According to GOST 2477

8

Mass fraction of paraffin, %, not more than

-

5,0

-

According to GOST 17789 and ГОСТ 28967

9

Penetration index

-

From 1.0 to 2.5

-

 

10

Needle penetration depth at 25 °C in the residue after heating, % of the initial value, not less than

60

60

70

According to GOST 11501

 

 

Roofing bitumens have a higher softening temperature (85 - 95 C) and a smaller depth of needle penetration, while for insulating bitumens the extensibility index is important. It is usually prepared from residual bitumen of low density. Roofing bitumen contains a certain amount of cycloparaffin and paraffin hydrocarbons and approximately 30% asphaltenes. The ratio of carbon and hydrogen in it is also increased; as a result, the dissolving capacity of such bitumens decreases and the mutual attraction of asphaltenes increases. 

Asphaltenes also attract heavy aromatic components, but the probability of other components joining with these aggregates is very low. Such a system can be considered at high temperatures as a concentrated solution of a solid substance in an oil medium. When cooled, the asphaltenes precipitate and form complexes that resemble crystallites. This process is so rapid that the aggregates are extremely small; this corresponds to the general law that the ratio of the surface of a crystal to its volume is greatest at high growth rates.

An equally important factor determining the quality of bitumen is the method of its production. The production of roofing bitumen in the practice of oil refining both in Ukraine and abroad is carried out mainly by oxidation of the corresponding oil residual products. In Ukraine, the main amount of oxidized bitumen is produced in batch cubes.

For most bitumens, the ability to water saturation is revealed already during the first day. Therefore, the technical requirements of GOST 9812 - 61 for petroleum roofing bitumens are limited to standardization of daily water saturation of bitumen. Studies of bitumens show that their physical and chemical properties are related to the fractional composition.

Knowledge of the optimal ratios of individual components of raw materials, as well as colloidal changes occurring during the production of bitumen, makes it possible to take a more qualified approach to the selection of raw materials and the method of processing them to obtain high-quality bitumen.However, the quality requirements for oils for the production of insulating bitumens differ significantly from the requirements for them for obtaining road bitumens. This is due to the specifics of their application, as well as the difference in the structural and colloidal state of viscous and solid bitumens.